It must be the Combat Phase, and while you are making attacks with your units.
It can be in any order within your units attacking. You can attack with one unit, then do a battlefield support attack, then two more of your units attack, and then two battlefield support attacks, etc.
You can't attack, even with battlefield support, during another player's attacks. If you lost initiative and are making your attacks first, you can't do a battlefield support attack after your opponent attacks, you've already made your attacks.
Which battlefield support attacks you use each turn are up to you. You can use one, all or none in a turn. You can just use each once in the game.
They do not replace any other attacks by your units.