Here are the most current rulebooks and printings:
Total Warfare - 10th printing
TechManual - 6th printing
Tactical Operations: Advanced Rules - 3rd Printing
Tactical Operations: Advanced Units and Equipment - 3rd Printing
Strategic Operations: Advanced Aerospace - 2nd printing
Campaign Operations - 3rd printing
Interstellar Operations: Alternate Eras - 3rd printing
Interstellar Operations: BattleForce - 3rd printing
A Time of War - 3rd Printing
BattleMech Manual - 6th printing*
Alpha Strike: Commander's Edition - 5th printing**
*This is a combination of the 'Mech rules from total warfare plus some of the equipment and rules from the Tactical Operations volumes for 'Mech-only battles
**Alpha Strike is a more abstracted ruleset that plays faster and allows for games with substantially more units
Note that the subtitles matter. Tactical Operations, Strategic Operations, and Interstellar Operations without the above subtitles are old versions. They're not completely obsolete, but enough has been shifted around and revised that using them can be a chore while chasing errata and other changes.