Pretty sure it is almost always just black inside. While a barrel could be chrome lined, that probably would be really visible, though perhaps a slight chrome ring and black center could work. Or gray rather than chrome. Then again, they're probably somewhat sooty so there might not be any other color than black or very dark gray.
I mean, cannons don't glow, unless they're firing, and in this case you'd probably want some kind of muzzle flash/smoke effect part.
That said, i did just get an idea, perhaps yellow-orange-red gradient (center to outside) to suggest the gun's very very hot?
EDIT Looking at what CamoSpecs folks do, autocannons seem to be black basically always.